Advances in Organometallic Chemistry, 7 by F G A Stone; Robert West

By F G A Stone; Robert West

ADVANCES ORGANOMETALLIC CHEMISTRY V 7.

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Sci. [2] 25, No. 8, 820 (1963). 19. , Proc. 9th Robert A. Welch Found. Conf. Chem. , Houston, Texas, 1966 p. 7. 20. , p. 747. Reinhold, New York, 1966. 21. , Atwell, W. , and Cartledge, F. , Adwan. Organometal. Chem. 4, 1 (1 966). 22. , and Dunn, G. , Chem. Rew. 52, No. 1, 77 (1953). 23. , and Eisch, J. , Sci. Am. 208, No. 1 , 89 (1963). 24. , and Heckert, L. , J . Am. Chem. 42,1010 (1920). 25. , Jones, R. , Martin. G. , Nobis, J. , Thirtle, J. , Yale, H. , and Yeoman, F. , J. Am. Chem. SOC. 78, 2790 (1956); and subsequent papers in this series.

Chem. , Houston, Texas, 1966 p. 7. 20. , p. 747. Reinhold, New York, 1966. 21. , Atwell, W. , and Cartledge, F. , Adwan. Organometal. Chem. 4, 1 (1 966). 22. , and Dunn, G. , Chem. Rew. 52, No. 1, 77 (1953). 23. , and Eisch, J. , Sci. Am. 208, No. 1 , 89 (1963). 24. , and Heckert, L. , J . Am. Chem. 42,1010 (1920). 25. , Jones, R. , Martin. G. , Nobis, J. , Thirtle, J. , Yale, H. , and Yeoman, F. , J. Am. Chem. SOC. 78, 2790 (1956); and subsequent papers in this series. 26. , in “Encyclopaedia Britannica,” Vol.

It is interesting that studies concerned with the preparation and possible resolution of optically active isomers have played a significant role in a number of cases, particularly with organolead and with organosilicon compounds. T h e extended and beautiful work by E. Krause on organolead chemistry was motivated by his interest in this direction. I n order to prepare initially an asymmetric molecule such as R'R2R3PbX, it was necessary to build a chemistry of organolead compounds. It was relatively easy to prepare compounds such as RIPb and R,PbX, but how to make a compound such as R1RZR3PbX?

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