By Chang-Ha Lee
A presentation of analysis on adsorption technological know-how and expertise. It serves as a reference for study in components resembling basics of adsorption and ion trade (equilibria and kinetics), new fabrics, adsorption characterization, novel tactics, strength and environmental procedures. The papers are taken from the 3rd Pacific Basin convention on Adsorption technology and know-how, held in Korea in 2003.
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Extra info for Adsorption Science and Technology: Proceedings of the 3rd Pacific Basin Conference Kyongju, Korea May 25-29 2003
Smit, Understanding Molecular Simulation: From Algorithms to Applications 2"* Edition (Academic Press, London, 2002) ["I A. Chelkowski, Dielectric Physics (Elsevier, North-Holland, New York 1980) I'[ D. Morineau, G. Dosseh, C. Alba-Simionesco and P. Llewellyn, Glass Transition, Freezing and Melting of Liquids Confined in the Mesoporous Silicate MCM-41, Philos. Mag. B 79 (1999) pp. 1847-1855 ["I G. Dosseh, D. Morineau and C. Alba-Simionesco, Benzene Confined in MCM-41 Below its Melting Point: A Proton NMR Study, J.
The pore diameters are uniform and tailorable, typically, in the range between 2 and 10 nm. These carbons show many new possibilities for applications to adsorbents, catalysts and electrode materials. Particularly for adsorption studies, it is expected that the well-defined mesoporous structures would be also useful as a reference pore system for the development of characterization methods and theoretical modeling for the adsorption on carbon surfaces. 1 INTRODUCTION The microporous (pore diameters less than 2 nm) and mesoporous (2-50 nm) carbons are widely used in many areas of modem science and technology, including water and air purification, gas separation, catalysts preparation, chromatography, fuel storage, and manufacturing of electrochemical devices [ 1,2].
4 (a) Comparisonof PFG hMR data (325K)and mcer ZLC &fa (358IQ for propane and propene inNaX oeoiite crystals . (b) Cmpakon of PFG W R , FR and mer ZLC difbivities for bepane-wax at 468K (201. E-08 . E ‘ x 0- b e +- F R a . 1 1331 D = S . E-09 . 0 NZLCTrmsD. 1 33 4ooofr Fig. 5 krhenius plot showing comparison between ZLC and FR diffusivitits for bmzene in silicalite. Data from 116 and 31-331 D or o0 i m ‘s-’ 10% 109 1o-’O lo-” 1010-’3 0 2 4 6 8 10 12 14 16 18 Number of carbon atoms Fig. simulations, (e) hierarchical simulation, QENS, (V)skgie crystal membrane.